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INTRODUCTION
As a
hexahydric alcohol, sorbitol is a member of the polyhydric
alcohol family the lowest of which are ethylene glycol and
glycerol. The close chemical relationship between Sorbitol
and the lower alcohols (like glycol and glycerol) is responsible
for the similarity in their general physical properties and
applications in industrial technology.
USES
In general, hexitols and their derivates particularly sorbitol,
are used in diverse industries viz. pharmaceuticals, cosmetics,
toothpastes, cigarette, foods, textiles, adhesives, cigarette,
foods, confectionery, printing ink, etc. One of the major
uses of Sorbitol is as an humectant
and conditioning agent. Many products under day-to-day atmospheric
changes require the addition of a humectant to assist
them to retain their freshness, softness and flexibility and
to maintain ideal manufacturing conditions.
To summarise, the principal advantages which Sorbitol exhibits
over other polyols are -
- Sorbitol GIVES UP water very slowly to a drier atmosphere.
- Sorbitol TAKES UP water very slowly from a humid atmosphere.
CONFECTIONERY :
In candy manufacture, Sorbitol is used together with sugar to increase shelf-life.
The function of Sorbitol is to retard the solidification of
sugar often associated with staleness in candy. It also helps
to improve softess, taste and texture. In butter creams, an
additional benefit is enhanced flavour. Sorbitol may be used
in diabetic chocolates. Sorbitol is used as a humectant and
softner in shredded coconut, its decided advantage over sugar
being that the darkening of the product does not occur. A
small quantity of 70 % Sorbitol added to peanut butter has
been shown to reduce dryness and crumbleness and improve spreadability.
TEXTILES :
Sorbitol functions in textile in applications basically as
a dispensing agent, humectant, bodying agentand sequestering
agent. In printing, a paste of 2 % to 3 % Sorbitol liquid
70 % (on the weight of the gum in the dye paste) prevents
livering of the paste. Improves brightness & intensity
of colour assists penetrations, prevents bleeding and promotes
leveling.
In textile sizing, Sorbitol acts as a humectant, and especially in winter it
preserves the film of the adhesive from becoming dry and maintain
its plasticity. In scouring operations, it mainly acts as
a sequestering agent. In finishing, it gives a soft feel,
good drape and proven dimension stability to the fabric.
TOBACCO :
The moisture content of cigarettes is very important, and change in moisture
content, due to change in humidity, is minimised if Sorbitol
is used as a conditioner.Also Sorbitol is non- volatile and
hence there is no danger of losing the conditioner during
drying and other processing operations. Sorbitol is compatible
with various ingredients used in tobacco mixture. Because
of its sweetness and cooling taste, Sorbitol contributes to
the flavour of chewing tobacco besides conditioning the product.
SPECIFICATIONS
| Liquid Sorbitol
70 % of the following specifications and general properties:
|
| Appearance |
Colourless
to faint |
| |
Yellow
syrupy liquid |
| D
Sorbitol in 100 g |
More
than 64 g. |
| Refractive
index at 20 oC |
1.445
to 1.465 |
| Specific
gravity at 20 oC |
1.285 |
| Sulfated
ash % by weight max. |
0.1 |
| Reducing sugar % (as glucose) by
weight max. |
0.2 |
| PH |
6
to 7 |
| Arsenic
parts per million max. |
3
ppm |
| Heavy
metals (as lead) parts per millon |
10
ppm |
| Chloride
max. |
50
ppm |
| Sulphate
max. |
100
ppm |
ADHESIVES :
Sorbitol is the ideal answer since it neither loses nor absorbs any appreciable
quantity of water, unlike conventional humectant like glycerine
or ethylene glycol sorbitol increases the viscosity of the
glue composition so that more water is needed, resulting in
greater economy.
Sorbitol functions as a moisture conditioning agent and its non-volatility
ensures non-cracking labels and envelops with minimum of curling.
PHARMACEUTICALS :
Sorbitol finds use as a bodying agent in pharmaceuticals
syrups and elixirs. The use of Sorbitol in cough syrups reduces
the tendency of the bottle caps to stick due to the crystallization
of the sugar present. Sorbitol is a good humectant and plasticiser
and these properties make it useful in emulsion ointments,
non - fat soluble ointments and gelatine capsules. Ointments,
creams and pastes will show satisfactory spreading capacity
with Sorbitol as adjuvant. Aqueous Sorbitol Solutions are
not subject to fermentative decomposition, and that is why
Sorbitol finds increasing use in the preparation of dental
formulations for buccal cavity.
COSMETICS :
Sorbitol is widely used in cosmetics, both as a humectant to retard loss of
water from O/W type of creams and as an emollient.
Sorbitol liquid 70 % has proved a useful additive for improving
the aesthetic appeal of glycerine carbolic soap by imparting
better transparency. Generally speaking, Liquid Sorbitol 70
% can replace other humectants, weight by weight where the
humectant percentage is less than 10 %.
TOOTHPASTES :
Sorbitol effectively replaces glycerine and sugar in toothpastes,
imparting the required degree of plasticity and sweetness.
This usage is based on the alkali stability, sweetness, humectant
and plasticising properties of Sorbitol.
SKIN CREAM AND CREAM FOUNDATION :
Sorbitol replaces glycerine as a humectant and conditioning
agent and helps to reduce the greasiness as well as the particle
size of the disperse phase.
EMULSIONS :
Sorbitol retards the loss of water by evaporation from oil
in water emulsion and is more effective than glycerine of
the same concentration when this is less than 10 %.
FOODS :
Sorbitol imparts to frozen desserts, body and textures as
well as some sweetness. Sorbitol is used in frozen desserts
for diabetics because it is slowly absorbed from the intestine
and is metabolised as fructose. In the manufacture of sugarless
chewing gum, Sorbitol provides the water-soluble solids; further
a 70 % solution of Sorbitol in water provides proper plasticity.
Sorbitol resists fermentation of acids by microorganisms in
the mouth, and therefore it is believed not to contribute
to the incidence of dental caries. In artificially sweetened
canned fruits, the addition of Sorbitol syrup provides body
and also reduces the undesirable after - taste of saccharine.
In low -caloric soft drinks, Sorbitol finds use as a bodying
agent in addition to its use as a sequestering agent in canned
soft drinks.
DIABETIC DIETS :
Extensive research has led to the adoption of Sorbitol to substitute sugar as
a sweetening agent in diabetic diets.
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